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Phenylene-bridged bis(benzimidazolium) (BBIm2+): a dicationic organic photoredox catalyst

JOURNAL ARTICLE published 2020 in Chemical Science

Research funded by Japan Society for the Promotion of Science (19K15564,20H04818,20H04819)

Authors: Takuya Kodama | Maiko Kubo | Wataru Shinji | Kei Ohkubo | Mamoru Tobisu

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JOURNAL ARTICLE published 2020 in Chemical Science

Cyclization of interlocked fumaramides into β-lactams: experimental and computational mechanistic assessment of the key intercomponent proton transfer and the stereocontrolling active pocket

JOURNAL ARTICLE published 2021 in Chemical Science

Research funded by Ministerio de Economía y Competitividad (CTQ2017-87231-P,RYC-2017-22700) | Universidad Autónoma de Madrid (RES-QSB-2019-3-0012) | Fundación Séneca (20811/PI/18)

Authors: Alberto Martinez-Cuezva | Aurelia Pastor | Marta Marin-Luna | Carmen Diaz-Marin | Delia Bautista | Mateo Alajarin | Jose Berna

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JOURNAL ARTICLE published 2020 in Chemical Science

A reduced-dimensional polar hybrid perovskite for self-powered broad-spectrum photodetection

JOURNAL ARTICLE published 2021 in Chemical Science

Research funded by National Natural Science Foundation of China (21971238,21833010,21525104,21875251,21975258,61975207,21921001) | Chinese Academy of Sciences (ZDBS-LY-SLH024,XDB20010200) | Natural Science Foundation of Fujian Province (2018H0047)

Authors: Dong Li | Wentao Wu | Shiguo Han | Xitao Liu | Yu Peng | Xiaoqi Li | Lina Li | Maochun Hong | Junhua Luo

Selective cleavage of unactivated arene ring C–C bonds by iridium: key roles of benzylic C–H activation and metal–metal cooperativity

JOURNAL ARTICLE published 2021 in Chemical Science

Research funded by Leverhulme Trust (RPG-2018-406) | Engineering and Physical Sciences Research Council (EP/ L000075/1)

Authors: Yancong Tian | Martin Jakoobi | Roman Boulatov | Alexey G. Sergeev

The structure of human dermatan sulfate epimerase 1 emphasizes the importance of C5-epimerization of glucuronic acid in higher organisms

JOURNAL ARTICLE published 2021 in Chemical Science

Research funded by Knut och Alice Wallenbergs Stiftelse (KAW 2016.0023) | Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung (P2ZHP3_191289)

Authors: Mahmudul Hasan | Hamed Khakzad | Lotta Happonen | Anders Sundin | Johan Unge | Uwe Mueller | Johan Malmström | Gunilla Westergren-Thorsson | Lars Malmström | Ulf Ellervik | Anders Malmström | Emil Tykesson

Construction of chiral α-tert-amine scaffolds via amine-catalyzed asymmetric Mannich reactions of alkyl-substituted ketimines

JOURNAL ARTICLE published 2021 in Chemical Science

Research funded by Japan Society for the Promotion of Science (JP26220803,JP18H01975,JP20H04815)

Authors: Chihiro Homma | Aika Takeshima | Taichi Kano | Keiji Maruoka

An excited state dynamics driven reaction: wavelength-dependent photoisomerization quantum yields in [Ru(bpy)2(dmso)2]2+

JOURNAL ARTICLE published 2020 in Chemical Science

Research funded by National Science Foundation (CHE 1602240,CHE 1856492)

Authors: Maksim Y. Livshits | Lei Wang | Sebastian B. Vittardi | Stefan Ruetzel | Albert King | Tobias Brixner | Jeffrey J. Rack

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JOURNAL ARTICLE published 2020 in Chemical Science

Enthalpic incompatibility between two steric stabilizer blocks provides control over the vesicle size distribution during polymerization-induced self-assembly in aqueous media

JOURNAL ARTICLE published 2020 in Chemical Science

Research funded by Engineering and Physical Sciences Research Council (EP/R003009)

Authors: Deborah L. Beattie | Oleksandr O. Mykhaylyk | Steven P. Armes

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JOURNAL ARTICLE published 2020 in Chemical Science

Heterometallic multinuclear nodes directing MOF electronic behavior

JOURNAL ARTICLE published 2020 in Chemical Science

Research funded by U.S. Department of Energy (DE-SC0019360,DE-SC0016574) | National Science Foundation (OIA-1655740/20-GC03)

Authors: Otega A. Ejegbavwo | Anna A. Berseneva | Corey R. Martin | Gabrielle A. Leith | Shubham Pandey | Amy J. Brandt | Kyoung Chul Park | Abhijai Mathur | Sharfa Farzandh | Vladislav V. Klepov | Brittany J. Heiser | Mvs Chandrashekhar | Stavros G. Karakalos | Mark D. Smith | Simon R. Phillpot | Sophya Garashchuk | Donna A. Chen | Natalia B. Shustova

Correction: Visible-light photooxidation in water by 1O2-generating supramolecular hydrogels

JOURNAL ARTICLE published 2020 in Chemical Science

Authors: Sankarsan Biswas | Mohit Kumar | Andrew M. Levine | Ian Jimenez | Rein V. Ulijn | Adam B. Braunschweig

Anomalous chemically induced electron spin polarization in proton-coupled electron transfer reactions: insight into radical pair dynamics

JOURNAL ARTICLE published 2020 in Chemical Science

Research funded by National Science Foundation (CHE–1900541)

Authors: Alexander M. Brugh | Malcolm D. E. Forbes

N2Phos – an easily made, highly effective ligand designed for ppm level Pd-catalyzed Suzuki–Miyaura cross couplings in water

JOURNAL ARTICLE published 2020 in Chemical Science

Research funded by Materials Research Science and Engineering Center, Harvard University (NSF DMR 1720256) | National Science Foundation (18-56406,CNS-1725797)

Authors: Nnamdi Akporji | Ruchita R. Thakore | Margery Cortes-Clerget | Joel Andersen | Evan Landstrom | Donald H. Aue | Fabrice Gallou | Bruce H. Lipshutz

Photocatalytic redox-neutral hydroxyalkylation of N-heteroaromatics with aldehydes

JOURNAL ARTICLE published 2020 in Chemical Science

Research funded by Japan Society for the Promotion of Science (17H06444,18H05969,19J23073,20H02754,20K15955,JP17H06442)

Authors: Hiromu Fuse | Hiroyasu Nakao | Yutaka Saga | Arisa Fukatsu | Mio Kondo | Shigeyuki Masaoka | Harunobu Mitsunuma | Motomu Kanai

Subcellular localised small molecule fluorescent probes to image mobile Zn2+

JOURNAL ARTICLE published 2020 in Chemical Science

Authors: Le Fang | Michael Watkinson

Efficient cleavage of tertiary amide bonds via radical–polar crossover using a copper(ii) bromide/Selectfluor hybrid system

JOURNAL ARTICLE published 2020 in Chemical Science

Research funded by Japan Society for the Promotion of Science (JP26220803,JP17H06450)

Authors: Zhe Wang | Akira Matsumoto | Keiji Maruoka

Delfos: deep learning model for prediction of solvation free energies in generic organic solvents

JOURNAL ARTICLE published 2019 in Chemical Science

Research funded by Ministry of Science, ICT and Future Planning (NRF-2017M3D1A1039553)

Authors: Hyuntae Lim | YounJoon Jung